Autore
PAOLO CROTTI
Unimap Dati autore
- Professore Ordinario presso Dipartimento di Scienze Farmaceutiche
- Membro della Facolta' di Farmacia
- Settore scientifico disciplinare CHIM/06 CHIMICA ORGANICA
- In servizio
Prodotti
- Articoli
- A Novel Effective Transition Metal Based Salt-Catalyzed Azidolysis of 1,2-Epoxides 1996
- An Efficient Stereoselective Synthesis of the Amino Sugar Component (E Ring) of Calicheamicin g1I 1996
- Efficient Application of Lipase-Catalyzed Transesterification to the Resolution of g-Hydroxy Ketones 1996
- Metal Salt-Catalyzed Addition of Lithium Enolates of Ketones to 1,2-Epoxides. An Efficient Route to a-Alkyl-g-Hydroxy Ketones 1996
- (Salen)Cr(III) Complex-Promoted Asymmetric Addition of Lithium Enolate of Acetophenone to Symmetrical 1,2-Epoxides 1997
- Aromatic Substituent Effect on the Stereoselectivity of the Condensed- and Gas-Phase Acid-Induced Methanolysis in 2-Aryloxiranes Derived from 3,4-Dihydronaphthalene and trans-1,2,3,4,4a,10a-Hexahydrophenanthrene Bearing a Tertiary Benzylic Oxirane Nucleop 1997
- Difunctionalised Oxirane Systems. Stereodivergent Synthesis of 1,4;2,3-dianhydro-5-O-benzyl-L-lyxitol and L-ribitol 1997
- Improved Stereoselective Synthesis of Both Methyl a- and b-Glycosides Corresponding to the Amino Sugar Component of the E Ring of Calicheamicin g1I and Esperamicin A1 1997
- Regiochemical Control of the Ring Opening of 1,2-Epoxides by Means of Chrelating Processes.XII. Synthesis and Ring-Opening Reactions of cis- and trans-Oxides Derived from cis 2-(Benzyloxy)-6-methyl-3,6-dihydro-2H-pyran 1997
- Regiochemical Control of the Ring Opening of Aziridines by Means of Chelating Processes.2. Synthesis and Ring-Opening Reactions of Aziridines Derived from 5,6-Dihydro-2H-pyran and of the Diastereoisomeric cis- and trans-Aziridines Derived from 3-(Benzylox 1997
- An Efficient Stereoselective Synthesis of Optically Pure Aziridine Derivatives of Allyl b-D-Glucopyranosides Asymmetrically Induced by the Glucide Moiety 1998
- Catalytic Enantioselective Carbon-Carbon Bond Formation by Addition of Dialkylzinc Reagents to Cyclic 1,3-Diene Monoepoxides 1998
- Synthesis and Ring-Opening Reactions of the Diastereoisomeric cis- and trans-Epoxides Derived from 3-(Benzyloxy)cyclopentene and 2-(Bensyloxy)-2,5-dihydrofuran 1998
- A New Diastereo- and Enantioselective Copper-Catalyzed Conversion of Alkynyl Epoxides into a-Allenic Alcohols 1999
- Regio- and Stereoselectivity in the Cyclization of Enolates Derived from 4,5-, 5,6-, and 6,7-Epoxy-1-phenyl-1-alkanones. Competition Between C- and O-Alkylation 1999
- A Versatile Periodate-Coupled Fluorogenic Assay for Hydrolytic Enzymes 2000
- A new catalytic and enantioselective desymmetrization of symmetrical methylidene cycloalkene oxides 2000
- Regiochemical control of the ring opening of 1,2-epoxides by means of chelating processes. XIV. Regioselectivity of the opening reactions with MeOH of remote O-substituted 1,2-epoxycyclohexanes under gas-phase operating conditions 2000
- A multigram, catalytic and enantioselective synthesis of optically active 4-methyl-2-cyclohexen-1-one: a useful chiral building block. 2001
- Efficient enantioselective synthesis of (R)-2-acetyl-2-hydroxy-5,8-dimethoxy-1,2,3,4-tetrahydronaphthalene, the key intermediate in the synthesis of anthracycline antibiotics 2001
- Enzyme fingerprints by fluorogenic and chromogenic substrate arrays 2001
- Highly enantioselective regiodivergent and catalytic kinetic resolution. 2001
- Stereo- and regioselectivity of cyclization reactions in conformationally restricted epoxy ketones: evaluation of C-versus O-alkylation process 2001
- Unprecedented catalytic enantioselective trapping of arene oxides with dialkylzinc reagents 2001
- Enzyme fingerprints of activity and stereo- and enantioselectivity from fluorogenic and Chromogenic Substrate arrays 2002
- New stereoselective beta-glycolsylation via a vinyl oxirane derived from D-glucal 2002
- Regiochemical Control of the Ring Opening of Aziridines by Means of Chelating Prccesses. Part.3: Regioselectivity of the Opening Reactions with Methanol of Remote O-Substituted Regio- and Diastereoisomeric Activated Aziridines under Condensed- and Gas-ph 2002
- Regiochemical control of the ring opening of 1,2-epoxides by means of chelating processes. Part 17: Synthesis and opening reactions of cis- and trans- oxides derived from (2S,6R)-2-benzyloxy-6-methyl-3,6-dihydro-2H-pyran, (2R,6R)- and (2S, 6R)-2-methoxy-6 2002
- Catalytic Enantioselective Desymmetrization of COT-Monoepoxide. Maximum Deviation from Coplanarity for an SN2’-Cuprate Alkylation 2003
- Copper-Catalyzed Addition of Organometallic Reagents to Vinyl Diepoxides. A Novel Entry to Oxabridged Systems and to Substituted Allylic Alcohols 2003
- New Stereoselective b-C-Glycosidation by Uncatalyzed 1,4-Addition of Organolithium Reagents to a Glycal-derived Vinyl Oxirane 2003
- Regiochemical control of the ring opening of 1,2-epoxides by means of chelating processes. Part 15: Regioselectivity of the opening reactions with MeOH of remote O-substituted regio- and diastereoisomeric pyranosidic epoxides under condensed- and gas-phase operating conditions 2003
- A DFT Investigation of the Addition Reaction of Monomeric Lithium Enolate Derived from Propiophenone to Propene Oxide: Examination of the Possible Transition Structures 2004
- Catalytic Regiodivergent Kinetic Resolution of Allylic Epoxides: A New Entry to Allylic and Homoallylic Alcohols with High Optical Purity 2004
- Fluorescence Assay and Screening of Epoxide Opening Reactions by Nucleophiles 2004
- Regio- and Stereoselectivity of the Addition of O-, S-, N-, and C-Nucleophiles to the beta Vinyl Oxirane Derived from D-Glucal 2004
- Simple Synthetic Transformations of Highly Enantioenriched 4-Alkyl-2,5,7-Cyclooctatrienols into Functionalized Bicyclo[4.2.0]octa-2,4-dienes and 2,6-Cyclooctadienones 2004
- Stereospecific Uncatalyzed a-O-Glycosilation and a-C-glycosilation by Means of a New D-Gulal-Derived alpha Vinyl Oxirane 2004
- "Regiochemical Control of the ring opening of 1,2-epoxides by means of chelating processes. Part 18. Regioselectivity of the opening reactions with MeOH of 1-(benzyloxy)-2,3- and -3,4-epoxyalkanes under condensed and gas phase operating conditions" 2005
- Catalytic asymmetric ring opening of 2,3-substituted norbornenes with organometallic reagents: a new formal aza-functionalization of cyclopentadiene 2005
- Copper-Catalyzed Highly Enantioselective Synthesis of Cyclic Allylic and Homoallylic Alcohols with Dialkylzinc Reagents 2005
- MMild metal-free syn-stereoselective ring opening of activated epoxides and aziridines with aryl borates 2005
- Methanolysis of 1-aryl-1,2-epoxycyclohexanes in the condensed and in the gas phase: importance of the substituent for the reaction mechanism 2005
- Stereoselective Synthesis of 4-(N-Mesylamino)-2.3-unsaturated- a-O-glycosides via a New Glycal-Derived Vinyl a-N-(Mesyl)-aziridine 2005
- A new regio- and stereoselective intermolecular Friedel-Craft alkylation of phenolic substrates with aryl epoxides 2006
- Catalytic asymmetric ring-opening of cyclopentadiene-heterodienophile cycloadducts with organometallic reagents 2006
- Facile Regio- and Stereoselective Carbon-Carbon Coupling of Phenol Derivatives with Aryl Aziridines. 2006
- Stereoselective Uncatalyzed Synthesis of 2,3-Unsaturated-4-N-substituted-b-O-glycosides by Means of a New D-Galactal Derived N-(Mesyl)-aziridine 2006
- Mild and stereoselective Friedel-Craft alkylation of phenol derivatives with vinyl oxiranes: a new access to cycloalkenobenzofurans 2007
- N-Nosyl as a stereoselectivity-improving and easily removable group in the O-glycosylation of D-allal and D-galactal-derived allyl aziridines. Stereospecific synthesis of 4-amino-2,3-unsaturated-O-glycosides 2007
- Regiochemical control of the ring opening of aziridines by means of chelating processes 4. Regioselectivity of the opening reactions with MeOH of 1-(benzyloxy)-2,3- and 3,4-N-(methoxycarbonyl)-aziridoalkanes under condensed and gas-phase operatine conditions 2007
- Stereoselective Synthesis of 2,3-unsaturated-az-gycosides via new diastereoisomeric N-Cbz-imino glycal-derived allyl epoxides 2007
- Synthesis and Cyclodehydration of Hydroxyphenols: A New Stereoselective Approach to 3-Aryl-2,3-dihydrobenzofurans 2007
- Stereoselective Synthesis of 2,3-Unsaturated 1,6-Oligosaccharides by Means of a Glycal-Derived Allyl Epoxide and N-Nosyl Aziridine 2008
- Synthesis of diastereoisomeric 6-deoxy-D-allal- and 6-deoxy-D-galactal-derived allyl epoxides and examination of the regio- and stereoselectivity in nucleophilic addition reaction. Comparison with the corresponding 6-O-functionalized allyl epoxides 2008
- Regio- and Stereoselective Ring Opening of Allylic Epoxides 2009
- Stereoselective Synthesis of 4-Amino-2,3-unsaturated-N-Cbz-imino-O-glycosides via New Diastereoisomeric N-Cbz-Imino Glycal-Derived Allyl N-Nosyl Aziridines. 2009
- Theoretical conformational study of six-membered cyclic allyl epoxides 2009
- Aminolysis of Glycal-Derived Allyl Epoxides and Activated Aziridines. Effects of the Absence of Coordination Processes on the Regio- and Stereoselectivity 2010
- Chemical Reactivity Predictions: Use of Data Mining Techniques for Analyzing Regioselective Azidolysis of Epoxides 2010
- Stereoselective synthesis of 2-O-MEM-2,3-unsaturated-beta-O-glycosides and elaboration to useful synthetic tools 2010
- Stereoselective synthesis of beta-phenylselenoglycosides from glycals and rationalization of the selenoglycosylation processes 2010
- Copper-catalyzed divergent kinetic resolution of racemic allylic substrates. 2011
- Stereodivergent synthesis of diastereoisomeric carba analogs of glycal-derived vinyl epoxides: A new access to carbasugars. 2011
- Synthesis of carba analogs of 6-O-(benzyl)-D-allal-and-D-galactal-derived allyl epoxides and evaluation of the regio- and stereoselective behavior in nucleophilic addition reactions. 2011
- Atti, Riassunti o Comunicazioni
- Sistemi ossiranici difunzionalizzati. Sintesi Stereodivergente del 1,4:2,3-dianidro-5-O-benzil-L-Lixitolo e Ribitolo 1996
- Allil epossidi derivati da glicaali in processi reiterativi di O-glicosilazione stereoselettiva per la sintesi di 1,6-oligosaccaridi 2,3-insaturi 2006
- Regio- and Stereoselectivity of the Addition Reactions of Nucleophiles to the Distereoisomeric D-Allal- and D-Galactal-Derived Allyl Epoxides and Aziridines 2006
- Synthesis of the diastereoisomeric iminoglycal-derived allyl epoxides and study of the regio-and stereoselectivity in addition reactions with O-nucleophiles 2006
- A new Completely Stereoselective Synthesis of 2-alkoxy-2,3-unsaturated O-glycosides 2008
- STEREOSELECTIVE SYNTHESIS OF (±)-4-AMINO-4,6-DIDEOXY-2,3-UNSATURATED AZA-O-GLYCOSIDES VIA NEW DIASTEREOISOMERIC (±)-6-DEOXY-N-Cbz-IMINO GLYCAL-DERIVED ALLYL N-NOSYL AZIRIDINES 2008
- Stereoselective Synthesis of 4-amino-6-deoxy-2,3-unsaturated Aza-O-glycosides via a new diastereoisomeric 6-deoxy-N-Cbz-Iminoglycal-derived allyl N-Nosyl aziridines 2008
- Brevetti
- Capitoli, Parte,Saggi, Studi, Articoli in libro
- Utilization of Epoxides in the Synthesis of Natural Products - Seminars in Organic Chemistry 2000
- Regio- and Stereselective addition Reactions of Carbon Nucleophiles to epoxides - Targets in Heterocyclic Systems-Chemistry and Properties 2003
- Epoxides in Complex Molecule Synthesis - Aziridines and Epoxides in Organic Synthesis 2006